|
|
8-methylthiooctyl_glucosinolate + O2 + NADPH + H+ <=> 8-(methylsulfinyl)octyl-glucosinolate + H2O + NADP+
|
1.14.13.237
aliphatic glucosinolate S-oxygenase
|
–
|
| |
MetaCyc:
RXNQT-4338
|
|
|
|
4-methylthiononanaldoxime + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 1-(methylsulfanyl)-9-aci-nitrononane + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11419
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)nonan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)nonyl-thiohydroximate + L-seryl-glycine
|
4.4.1.M2
|
–
|
| |
MetaCyc:
RXN-11443
|
|
|
|
(E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)nonan-1-imine + H2O <=> (E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)nonan-1-imine + glycine
|
3.4.13.23
cysteinylglycine-S-conjugate dipeptidase
|
–
|
| |
MetaCyc:
RXN-19587
|
|
|
|
(E)-1-(L-cystein-S-yl)-N-hydroxy-omega-(methylsulfanyl)nonan-1-imine + H2O <=> (E)-omega-(methylsulfanyl)nonyl-thiohydroximate + pyruvate + NH3
|
4.4.1.13
cysteine-S-conjugate beta-lyase
|
–
|
| |
MetaCyc:
RXNQT-4323
|
|
|
|
(E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)nonan-1-imine + H2O <=> (E)-1-(L-cysteinylglycin-S-yl)-N-hydroxy-omega-(methylsulfanyl)nonan-1-imine + L-glutamate
|
3.4.19.16
glucosinolate gamma-glutamyl hydrolase
|
–
|
| |
MetaCyc:
RXN-11435
|
|
|
|
3''-phosphoadenylyl-sulfate + desulfo-8-methylthiooctyl_glucosinolate <=> adenosine_3,5''-bisphosphate + H+ + 8-methylthiooctyl_glucosinolate
|
2.8.2.38
aliphatic desulfoglucosinolate sulfotransferase
|
–
|
| |
BRENDA:
BS407936
KEGG:
R11888
MetaCyc:
RXNQT-4333
|
|
|
|
L-hexahomomethionine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> H2O + CO2 + oxidized_[NADPH-hemoprotein_reductase] + 4-methylthiononanaldoxime
|
1.14.14.42
homomethionine N-monooxygenase
|
–
|
| |
MetaCyc:
RXNQT-4313
|
|
|
|
UDP-glucose + (E)-omega-(methylsulfanyl)nonyl-thiohydroximate <=> desulfo-8-methylthiooctyl_glucosinolate + UDP + H+
|
2.4.1.195
N-hydroxythioamide S-beta-glucosyltransferase
|
–
|
| |
MetaCyc:
RXNQT-4328
|
|
|
|
1-(methylsulfanyl)-9-aci-nitrononane + glutathione <=> (E)-1-(glutathion-S-yl)-N-hydroxy-omega-(methylsulfanyl)nonan-1-imine + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11427
|
|
